SECTION 1. IDENTIFICATION
Product Name: Iron(II) Chloride Tetrahydrate
Product Number: All applicable American Elements product codes, e.g. FE2-CL-02-C.4HYD , FE2-CL-03-C.4HYD , FE2-CL-04-C.4HYD , FE2-CL-05-C.4HYD
Bạn đang xem: Iron(II) Chloride Tetrahydrate
CAS #: 13478-10-9
Relevant identified uses of the substance: Scientific research and development
Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351
Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)GHS05 CorrosionSkin Corr. 1C H314 Causes severe skin burns and eye damage.Eye Dam. 1H318 Causes serious eye damage.GHS07Acute Tox. 4 H302 Harmful if swallowed.Hazards not otherwise classifiedNo data availableGHS label elementsGHS label elements, including precautionary statementsHazard pictograms
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GHS05 GHS07Signal word: DangerHazard statementsH302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.Precautionary statementsP280Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P309IF exposed or if you feel unwell:P310Immediately call a POISON CENTER/doctor/…WHMIS classificationD2B – Toxic material causing other toxic effectsE – Corrosive materialClassification systemHMIS ratings (scale 0-4)(Hazardous Materials Identification System)Health (acute effects) = 3Flammability = 0Physical Hazard = 1Other hazardsResults of PBT and vPvB assessmentPBT: N/AvPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
SubstancesCAS No. / Substance Name:13478-10-9 Iron(II) chloride tetrahydrateIdentification number(s):EC number: 231-843-4
SECTION 4. FIRST AID MEASURES
Description of first aid measuresGeneral informationImmediately remove any clothing soiled by the product.If inhaled:Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.Seek immediate medical advice.In case of skin contact:Immediately wash with soap and water; rinse thoroughly.Seek immediate medical advice.In case of eye contact:Rinse opened eye for several minutes under running water. Consult a physician.If swallowed:Seek medical treatment.Information for doctorMost important symptoms and effects, both acute and delayedCauses severe skin burns.Causes serious eye damage.Indication of any immediate medical attention and special treatment neededNo data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing mediaSuitable extinguishing agentsUse carbon dioxide, extinguishing powder or foam. Water may be ineffective but may be used for cooling exposed containers.Special hazards arising from the substance or mixtureIf this product is involved in a fire, the following can be released:Hydrogen chloride (HCl)Metal oxide fumeAdvice for firefightersProtective equipment:Wear self-contained respirator.Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Keep unprotected persons away.Ensure adequate ventilationEnvironmental precautions:Do not allow material to be released to the environment without official permits.Methods and materials for containment and cleanup:Use neutralizing agent.Dispose of contaminated material as waste according to section 13.Ensure adequate ventilation.Prevention of secondary hazards:No special measures required.Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
HandlingPrecautions for safe handlingHandle under dry protective gas.Keep container tightly sealed.Store in cool, dry place in tightly closed containers.Ensure good ventilation at the workplace.Information about protection against explosions and fires:No data availableConditions for safe storage, including any incompatibilitiesRequirements to be met by storerooms and receptacles:No special requirements.Information about storage in one common storage facility:Store away from air.Store away from water/moisture.Store away from strong bases.Store away from oxidizing agents.Further information about storage conditions:Store under dry inert gas.This product is hygroscopic.This product is air sensitive.Keep container tightly sealed.Store in cool, dry conditions in well-sealed containers.Protect from humidity and water.Specific end use(s)No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.Control parametersComponents with limit values that require monitoring at the workplace:None.Additional information: No dataExposure controlsPersonal protective equipmentFollow typical protective and hygienic practices for handling chemicals.Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.Maintain an ergonomically appropriate working environment.Breathing equipment:Use suitable respirator when high concentrations are present.Protection of hands:Impervious glovesInspect gloves prior to use.Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.Penetration time of glove material (in minutes): No data availableEye protection:Tightly sealed gogglesFull face protectionBody protection:Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
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Information on basic physical and chemical propertiesAppearance:Form: CrystallineColor: Green-YellowOdor: OdorlessOdor threshold: No data available.pH: N/AMelting point/Melting range: No data availableBoiling point/Boiling range: No data availableSublimation temperature / start: No data availableFlammability (solid, gas): No data available.Ignition temperature: No data availableDecomposition temperature: No data availableAutoignition: No data available.Danger of explosion: No data available.Explosion limits:Lower: No data availableUpper: No data availableVapor pressure: N/ADensity at 20 °C (68 °F): 1.93 g/cm3 (16.106 lbs/gal)Relative density: No data available.Vapor density: N/AEvaporation rate: N/ASolubility in / Miscibility with Water at 20 °C (68 °F): 1600 g/l SolublePartition coefficient (n-octanol/water): No data available.Viscosity:Dynamic: N/AKinematic: N/AOther informationNo data available
SECTION 10. STABILITY AND REACTIVITY
ReactivityNo data availableChemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to be avoided:Decomposition will not occur if used and stored according to specifications.Possibility of hazardous reactionsReacts with strong oxidizing agentsConditions to avoidNo data availableIncompatible materials:AirWater/moistureBasesOxidizing agentsHazardous decomposition products:Hydrogen chloride (HCl)Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effectsAcute toxicity:Harmful if swallowed.Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.LD/LC50 values that are relevant for classification: No dataSkin irritation or corrosion: Causes severe skin burns.Eye irritation or corrosion: Causes serious eye damage.Sensitization: No sensitizing effects known.Germ cell mutagenicity: No effects known.Carcinogenicity:No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.Reproductive toxicity: No effects known.Specific target organ system toxicity – repeated exposure: No effects known.Specific target organ system toxicity – single exposure: No effects known.Aspiration hazard: No effects known.Subacute to chronic toxicity: No effects known.Additional toxicological information:To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
ToxicityAquatic toxicity:No data availablePersistence and degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableAdditional ecological information:Do not allow material to be released to the environment without official permits.Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.Avoid transfer into the environment.Results of PBT and vPvB assessmentPBT: N/AvPvB: N/AOther adverse effectsNo data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methodsRecommendationConsult official regulations to ensure proper disposal.Uncleaned packagings:Recommendation:Disposal must be made according to official regulations.Recommended cleansing agent:Water, if necessary with cleansing agents.
SECTION 14. TRANSPORT INFORMATION
UN-NumberDOT, IMDG, IATAUN3260UN proper shipping nameDOTRQ Corrosive solid, acidic, inorganic, n.o.s. (Iron(II) chloride tetrahydrate)IMDG, IATACORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Iron(II) chloride tetrahydrate)Transport hazard class(es)DOTClass8 Corrosive substances.Label8Class8 (C2) Corrosive substancesLabel8IMDG, IATAClass8 Corrosive substances.Label8Packing groupDOT, IMDG, IATAIIIEnvironmental hazards:N/ASpecial precautions for userWarning: Corrosive substancesEMS Number:F-A,S-BSegregation groupsAcidsTransport in bulk according to Annex II of MARPOL73/78 and the IBC CodeN/ATransport/Additional information:DOTHazardous substance:100 lbs, 45.4 kgMarine Pollutant (DOT):NoUN “Model Regulation”:UN3260, Corrosive solid, acidic, inorganic, n.o.s. (Iron(II) chloride tetrahydrate), 8, III
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixtureGHS GHS label elements, including precautionary statementsHazard pictogramsGHS05GHS07Signal word: DangerHazard statementsH302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.Precautionary statementsP280Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P309IF exposed or if you feel unwell:P310Immediately call a POISON CENTER/doctor/…National regulationsAll components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.All components of this product are listed on the Canadian Domestic Substances List (DSL).SARA Section 313 (specific toxic chemical listings)Substance is not listed.California Proposition 65Prop 65 – Chemicals known to cause cancerSubstance is not listed.Prop 65 – Developmental toxicitySubstance is not listed.Prop 65 – Developmental toxicity, femaleSubstance is not listed.Prop 65 – Developmental toxicity, maleSubstance is not listed.Information about limitation of use:For use only by technically qualified individuals.This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.Other regulations, limitations and prohibitive regulationsSubstance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.Substance is not listed.The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.Substance is not listed.Annex XIV of the REACH Regulations (requiring Authorisation for use)Substance is not listed.Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
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